WCO Explanatory Notes reproduced for reference. © World Customs Organization. Verify against official WCO publication.
29.05 -Acyclic alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. 2905.17 - Saturated monohydric alcohols : - - Methanol (methyl alcohol) - - Propan- 1-01(propyl alcohol) and propan-2-01 (isopropyl alcohol) - - Butan-1-01(n-butyl alcohol) - - Other butanols - - Octanol (octyl alcohol) and isomers thereof - - Dodecan-1-01 (lauryl alcohol), hexadecan-1-01 (cetyl alcohol) 2905.19 - - Other 2905.1 1 2905.12 2905.13 2905.14 2905.16 octadecan-1-01 (stearyl alcohol) - 2905.22 2905.29 2905.3 1 2905.32 2905.39 2905.41 and Unsaturated monohydric alcohols : - - Acyclic terpene alcohols - - Other - Diols : - - Ethylene glycol (ethanediol) - - Propylene glycol (propane-1,Z-diol) - - Other - Other polyhydric alcohols : - - 2-Ethyl-2-(hydroxymethy1)propane-1,3-diol (trimethylolpropane) 2905.43 - - Mannitol 2905.44 - - D-glucitol (sorbitol) 2905.45 - - Glycerol 2905.49 - - Other - Halogenated, alcohols : sulphonated, nitrated or nitrosated derivatives of acyclic 2905.5 1 - - E t h c h l o ~ ~( ~I~ NNo)l 2905.59 - - Other Acyclic alcohols are derivatives of acyclic hydrocarbons obtained by replacin one or more atoms of hydrogen by the are oxygenated compounds w ch react with acids giving the compounds B The alcohols may be primary (containing the characteristic group -CH20H), secondary containing the characteristic group XHOH) or tertiary (containing the characteristic group 6 cow. This heading covers the ac clic alcohols described below and their halogenated, sulphonated, nitrated, mtrosated, sulp ohalo enated, nitrohalogenated, nitrosul honated, nitrosulphohalo enated or other compound erivatives (e.g., the monochlorohy rins of glycerol and of ethy ene glycol). Aldehyde-bisulphite corn ounds and ketone-bisul hite compounds are classified as sulphonated derivatives of a? cohols, e.g., acetaldehy e sodium bisulphite, formaldehyde sodium bisulphite, valeraldehyde sodium bisul hite and acetone sodium bisulphite. The heading also covers metal alcoholates of alcohols o this heading and of ethanol. % f P 7' This headin excludes ethanol (ethyl. alcohol), whether or not pure (see Explanatory Notes to headings 22.07 and 2f.08). (A) SATURATED MONOHYDRIC ALCOHOLS odour; used in methyl alcohol) obtained (2) Propan-1-01 (propyl alcohol) and propan-2-01 (isopropyl alcohol). These products are colourless li uids. The latter is obtained by synthesis from propylene and is used in the preparation o acetone, and methacrylates, and as a solvent, etc. (3) Butan-1-01 (n-butyl alcohol) and other butanols (4 isomers). Colourless liquids, used in organic synthesis and as solvents. (4) Pentanol (amyl alcohol) and isomers thereof. There are eight possible isomers. Fermentation arnyl alcohol is chiefly obtained from fuse1 oil (also known as grain oil, oil, etc., heading 38.24) which is itself obtained during the alcohol. Amy1 alcohols may also be synthesised from the during the cracking of petroleum. (5) Hexanols and heptanols (hexyl and heptyl alcohol). (6) Octanol (octyl alcohol) and isomers thereof. (7) Dodecan-1-01 (lauryl alcohol), hexadecan-1-01 (cetyl alcohol) and octadecan-1-01 (stearyl alcohol). This heading excludes fatty alcohols of a purity of less than 90 % (calculated on the weight of the dry product) (heading 38.23). (B) UNSATURATED MONOHYDRTC ALCOHOLS (1) AUyl alcohol. (2) Ethylpropylallyl alcohol (2-ethyl-2-hexen- 1-01). (3) Oleyl alcohol. (4) Ac clic terpene alcohols, e.g., phytol. Terpene alcohols are fairly readily converted into hy o-aromatic compounds and are found in certain essential oils. Examples are geraniol, citronellol, linalool, rhodinol and nerol, used in perfumery. a: (C) DIOLS AND OTHER POLYHYDRIC ALCOHOLS (I) Diols (1) Ethylene glycol (ethanediol). A colourless, s py liquid with a faint, pungent odour. Used in the manufacture of nitroglycol (exp osive), as a solvent for varnishes, as an anti-freeze agent or in organic synthesis. r" (2) Propylene glycol (propane-1,2-diol). Colourless, viscous and hygroscopic liquid. (II) Other polyhydric alcohols (1) G l r l (pro me-1,2,3-triol). Glycerol (also known as glycerine) may be obtained eit er by puri cation of crude glycerol (e.g., by distillation, ion-exchange purification) or synthetically from propylene. R Glycerol has a sweet taste. It is in general colourless and odourless, but may sometimes have a slight yellowish shade. To fall in this heading, lycerol must have a purity of 95 % or more (calculated on the weight of the dry pro uct). Glycerol of lower purity (crude glycerol) is excluded (heading 15.20). d r I (2) 2-Eth I-2-(hydroxymethy1)pro ane-1,3-diol trimethylolpro me). Used in the manu acture of varnishes and af&d resins, synt etic drylng 01 s, urethane foams and coatings. (3) Pentaerythritol. White crystalline powder, used in the manufactme of explosives and plastics. (4) Mannitol. White crystalline powder or granules. Found in the ve etable kingdom (sap of the Fraxinus ornus); obtained by synthesis. Used as a mil laxative and in the manufacture of explosives (mannitol hexanitrate). f (5) D-glucitol (sorbitol). White crystalline powder which is hygroscopic. Used in perfumery, in the manufacture of ascorbic acid used in medicine) and of surfaceactive agents, as a substitute for glycerol an as a humectant (i-e., moistureconditioning agent). (6) Pentanetriol, hexanetriol, etc. This heading excludes sorbit01 of heading 38.24. (D) HALOGENATED, SULPHONATED, NITRATED OR NITROSATED DERIVATlVES OF ACYCLIC ALCOHOLS ( 1 Chloral hydrate (CC13CH(OH)2)(2,2,2-trichloroethane-l,l-dial). Colourless toxic crystals; used as a hypnotic and in organic synthesis. (2) Trichloro-tertiary-butyl alcohol; used in medicine. (3) Ethchlorvynol. A psychotropic substance - see the list at the end of Chapter 29.
Notes. 1.- Except where the context otherwise requires, the headings of this Chapter apply only to : (a) Separate chemically defined organic compounds, whether or not containing impurities; (b) Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (Chapter 27); (c) The products of headings 29.36 to 29.39 or the sugar ethers, sugar acetals and sugar esters, and their salts, of heading 29.40, or the products of heading 29.41, whether or not chemically defined; (d) The products mentioned in (a), (b) or (c) above dissolved in water; (e) The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; (f) The products mentioned in (a), (b), (c), (d) or (e) above with an added stabiliser (including an anti- caking agent) necessary for their preservation or transport; (g) The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a colouring or odoriferous substance or an emetic added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; (h) The following products, diluted to standard strengths, for the production of azo dyes : diazonium salts, couplers used for these salts and diazotisable amines and their salts. 2.- This Chapter does not cover : (a) Goods of heading 15.04 or crude glycerol of heading 15.20; (b) Ethyl alcohol (heading 22.07 or 22.08); (c) Methane or propane (heading 27.11); (d) The compounds of carbon mentioned in Note 2 to Chapter 28; (e) Immunological products of heading 30.02; (f) Urea (heading 31.02 or 31.05); (g) Colouring matter of vegetable or animal origin (heading 32.03), synthetic organic colouring matter, synthetic organic products of a kind used as fluorescent brightening agents or as luminophores (heading 32.04) or dyes or other colouring matter put up in forms or packings for retail sale (heading 32.12); (h) Enzymes (heading 35.07); (ij) Metaldehyde, hexamethylenetetramine or similar substances, put up in forms (for example, tablets, sticks or similar forms) for use as fuels, or liquid or liquefied-gas fuels in containers of a kind used for filling or refilling cigarette or similar lighters and of a capacity not exceeding 300 cm3 (heading 36.06); (k) Products put up as charges for fire-extinguishers or put up in fire-extinguishing grenades, of heading 38.13; ink removers put up in packings for retail sale, of heading 38.24; or (l) Optical elements, for example, of ethylenediamine tartrate (heading 90.01). 3.- Goods which could be included in two or more of the headings of this Chapter are to be classified in that one of those headings which occurs last in numerical order. 4.- In headings 29.04 to 29.06, 29.08 to 29.11 and 29.13 to 29.20, any reference to halogenated, sulphonated, nitrated or nitrosated derivatives includes a reference to compound derivatives, such as sulphohalogenated, nitrohalogenated, nitrosulphonated or nitrosulphohalogenated derivatives. Nitro or nitroso groups are not to be taken as “nitrogen-functions” for the purposes of heading 29.29. For the purposes of headings 29.11, 29.12, 29.14, 29.18 and 29.22, “oxygen function”, the characteristic organic oxygen-containing group of those respective headings, is restricted to the oxygen-functions referred to in headings 29.05 to 29.20. 5.- (A) The esters of acid-function organic compounds of sub-Chapters I to VII with organic compounds of these sub-Chapters are to be classified with that compound which is classified in the heading which occurs last in numerical order in these sub-Chapters. (B) Esters of ethyl alcohol with acid-function organic compounds of sub-Chapters I to VII are to be classified in the same heading as the corresponding acid-function compounds. (C) Subject to Note 1 to Section VI and Note 2 to Chapter 28 : (1) Inorganic salts of organic compounds such as acid-, phenol- or enol-function compounds or organic bases, of sub-Chapters I to X or heading 29.42, are to be classified in the heading appropriate to the organic compound; (2) Salts formed between organic compounds of sub-Chapters I to X or heading 29.42 are to be classified in the heading appropriate to the base or to the acid (including phenol- or enol- function compounds) from which they are formed, whichever occurs last in numerical order in the Chapter; and (3) Co-ordination compounds, other than products classifiable in sub-Chapter XI or heading 29.41, are to be classified in the heading which occurs last in numerical order in Chapter 29, among those appropriate to the fragments formed by "cleaving" of all metal bonds, other than metal- carbon bonds. (D) Metal alcoholates are to be classified in the same heading as the corresponding alcohols except in the case of ethanol (heading 29.05). (E) Halides of carboxylic acids are to be classified in the same heading as the corresponding acids. 6.- The compounds of headings 29.30 and 29.31 are organic compounds the molecules of which contain, in addition to atoms of hydrogen, oxygen or nitrogen, atoms of other non-metals or of metals (such as sulphur, arsenic or lead) directly linked to carbon atoms. Heading 29.30 (organo-sulphur compounds) and heading 29.31 (other organo-inorganic compounds) do not include sulphonated or halogenated derivatives (including compound derivatives) which, apart from hydrogen, oxygen and nitrogen, only have directly linked to carbon the atoms of sulphur or of a halogen which give them their nature of sulphonated or halogenated derivatives (or compound derivatives). 7.- Headings 29.32, 29.33 and 29.34 do not include epoxides with a three-membered ring, ketone peroxides, cyclic polymers of aldehydes or of thioaldehydes, anhydrides of polybasic carboxylic acids, cyclic esters of polyhydric alcohols or phenols with polybasic acids, or imides of polybasic acids. These provisions apply only when the ring-position hetero-atoms are those resulting solely from the cyclising function or functions here listed. 8.- For the purposes of heading 29.37 : (a) the term “hormones” includes hormone-releasing or hormone-stimulating factors, hormone inhibitors and hormone antagonists (anti-hormones); (b) the expression “used primarily as hormones” applies not only to hormone derivatives and structural analogues used primarily for their hormonal effect, but also to those derivatives and structural analogues used primarily as intermediates in the synthesis of products of this heading. Subheading Notes. 1.- Within any one heading of this Chapter, derivatives of a chemical compound (or group of chemical compounds) are to be classified in the same subheading as that compound (or group of compounds) provided that they are not more specifically covered by any other subheading and that there is no residual subheading named “Other” in the series of subheadings concerned. 2.- Note 3 to Chapter 29 does not apply to the subheadings of this Chapter.